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By Bancroft W. D.

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PHA films produced from coconut oil (PHA-C; low olefinic concentration), tallow (PHA-T; intermediate olefinic concentration), and soybean oil (PHA-So; high olefinic concentration) were solution cast and irradiated using a γ-emitter (cesium-137). The films were characterized by tensile testing before and after radiation treatment to compare the effect of γ-irradiation on the polymer tensile properties. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2001. 27 Experimental Materials All simple salts were obtained from Sigma Chemical Company (St.

40 Acknowledgement The authors thank Rob DiCiccio and Bina Christy for their technical assistance, as well as Dr. Alberto Nunez for performing the GC/MS analyses, Dr. Donald Thayer for performing the polymer irradiation, Dr. Peter Cooke for the electron microscopy, Ms. Janine Brouillette for the C-NMR, Dr. Jim Hampson for the supercritical fluid extraction, and Dr. Cheng-Kung Liu for the tensile testing. 13 References 1. Anderson, A. ; Dawes, E. A. Microbiol. Rev. 1990, 54, 450-472. 2. ; Gross, R.

3): 1. Tallow is composed of both a liquid and a solid fraction at room temperature. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2001. 34 OCH I 3 M = 202 I M - H 0 = 184 2 > M - H 0 - C H O H = 152 2 3 Ν® s 0- 1 52 m/z Figwre 2. Electron-impact mass spectrum of β-hydroxydecanoate methyl ester. The presence of an ion fragment with m/z = 103 is indicative of a β-hydroxyalkanoate methyl ester. (SOURCE: Reproduced with permission from ref. ; ACS Symposium Series; American Chemical Society: Washington, DC, 2001.

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Aromatic Substitution Products with Fluorine by Bancroft W. D.

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