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ISBN-10: 085186600X

ISBN-13: 9780851866000

ISBN-10: 1847555756

ISBN-13: 9781847555755

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Gilbert, M. Chanaa, and L. Giral, Tefruhedron Letters, 1977,4033.

P. , p. 1073. -N. Paik, J. Amer. Chem. ,1978,100,506. Wennerstrom, Actu. Chem. Scand. ( B ) ,1977,31,915. Botter, J. Jullien, J. M. Pechine, J. J. Piada, and D. Solgadi,J. Electron Spectrosc. Relat. , 1978,13,141(Chem. , 1978,88,169 224). N. Warrener, K. I. Gell, and M. N. Paddon-Row, Tetrahedron Letters, 1977,5 3 . " Unstable peroxides (28; R = M e or Ph) are formed by the reaction of singlet oxygen with the corresponding fulvenes. *' Three articles describe the preparation of azulenes from fulvenes: 6-dimethylaminofulvene (3 1)reacts with thiophen SS-dioxide to yield azulene (33; R = H ) in 33% yield by elimination of sulphur dioxide and dimethylamine from the primary 67r + 471-cycloadduct (32);215,6-dichloroazulene (33; R = Cl) is similarly formed (60%) from 3,4-dichlorothiophen SSNMe, ( - f - H + 0 2 s~ (31) '' -aml?

Soedinenii, 1977,1693. T. Horaguchi, Bull. Chem. Japan, 1977,50,3329. A . Couture, A. Lablache-Cornbier, and H. Ofenberg, Org. Photochem. , 1976,2,7. Divanford and M. M. Joullie, Org. Rep. Proced. , 1978,10,94. Bartok. K. Lakos-Lang, L. G . Bogatskaya, G . L. Karnalov, and A. V. Bogatskii, Doklady Akad. , 1977,234,590. ~' The Diels-Alder reaction of furan with maleic anhydride has been re-investigated. Both endo- and em-adducts are formed; the 7' 72 73 74 75 76 77 J. Srogl, M. Janda, I. Stibor, and Z.

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Aromatic and Heteroatomic Chemistry Volume 7

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